u‰‰ŽาF Kosmas PrassidesŽiUniversity of Sussexj “๚ŽžF @‚XŒŽ@‚P‚Q“๚i‹เj@@Œ฿Œใ‚SŽž‚R‚O•ช‚ฉ‚็ ๊ŠF ยŽRŠw‰@‘ๅŠw@—HŠw•”i‘Š–อŒดƒLƒƒƒ“ƒpƒXj‚k“‚UŠK@‚k‚U‚O‚RŽบ ‘่–ฺF uStrongly correlated fullerene-based solids: are there any surprises left?v —vŽ|F The study of strongly correlated electron systems is at the forefront of contemporary condensed matter research because such materials which include transition metal oxides (colossal magnetoresistive manganites, high Tc cuprates) and intermetallic heavy fermion systems display remarkable electronic properties that challenge existing theory for satisfactory explanations. The interplay between charge, lattice, orbital and magnetic degrees of freedom in all these systems can be tuned sensitively both physically (varying an external parameter like pressure or magnetic field) and chemically (changing the chemical composition). A prominent branch of strongly correlated electron systems is the family of metal intercalated fullerides, which display superconductivity at temperatures as high as 40 K. In this lecture, an overview of the structures and physical properties of selected fullerene-based architectures will be presented with particular attention paid (i) to ammonia co-intercalated metal fullerides which are located at the boundaries of metal-insulator transitions [1] and (ii) to rare-earth fullerides which present opportunities based on the coupling between the lanthanide and fulleride electronic structures [2]. [1] S. Margadonna, K. Prassides, H. Shimoda, T. Takenobu, and Y. Iwasa, Phys. Rev. B 2001, 64, 132414; S. Margadonna, E. Aslanis, and K. Prassides, J. Am. Chem. Soc. 2002, 124, 10146. [2] I. Margiolaki, S. Margadonna, K. Prassides, T. Hansen, K. Ishii, and H. Suematsu, J. Am. Chem. Soc. 2002, 124, 11288; T. Takenobu, D. H. Chi, S. Margadonna, K. Prassides, Y. Kubozono, A. N. Fitch, K. Kato, and Y. Iwasa, J. Am. Chem. Soc. 2003, 125, 1897; J. Arvanitidis, K. Papagelis, S. Margadonna, K. Prassides, and A. N. Fitch, Nature, 2003, accepted.